EXTENDED ABSTRACT: This study presents the development of novel optoelectronic functional materials using highthroughput engineering techniques. A high-throughput robotic approach is used to grid-search 160 mixed-cation mixed-halide perovskites. The high-quality big data approach allows to uniquely identify the most photo-thermal-stable perovskites under 65 °C/1-Sun illumination. By integrating the most stable perovskites into novel bilayer and polymer-acid-metal structure in perovskite solar cells, we successfully achieve stable unpackaged devices that retain 99% of its peak efffciency after 1450 h of continuous operation at 65 °C in a N2 under illumination [1-2]. A combinatorial magnetron sputtering system is designed with reciprocating rectangular targets, a narrow slit between the substrate and the target, and a quartz crystal microbalance feedback to control the deposition uniformity, resulting in a variation better than 3% across a 76 × 76 mm substrate [3]. Furthermore, the high-throughput anode screening technology was realized based on the above system, which can efffciently screen the best alloy ratio, construct a functional interface layer, effectively improve the stability of the anode, and inhibit the side reaction [4-5].

Keywords: high throughput; perovskite; stability; zinc anode; magnetron sputtering

REFERENCES:

[1] Y. Zhao and C. Jia, et al., Nat. Energy, 7, (2022) 144.

[2] J. Luo and C. Jia, et al., Nat. Commun., 15, (2024) 2002.

[3] Z. Yan, S. Wu, Y. Song, et al. Rev. Sci. Instrum., 91, (2020) 065107.

[4] M. Sun and C. Jia, et al., Adv. Funct. Mater., (2024) 2413456.

[5] Z. Yan, Q and Cheng, et al. SmartMat, (2024) in press.